trans-Dichloridobis(4-nitroaniline-κN 1)palladium(II)
نویسنده
چکیده
In the title compound, [PdCl(2)(C(6)H(6)N(2)O(2))(2)], the Pd(II) atom is coordinated in a distorted square-planar geometry by two N atoms from two 4-nitro-aniline ligands and two Cl atoms in a trans arrangement. Inter-molecular N-H⋯Cl hydrogen bonds involving the amino groups and chloride anions lead to a chain along [100]. These chains are further self-assembled into a three-dimensional network through N-H⋯O and N-H⋯Cl hydrogen bonds.
منابع مشابه
trans-Dichloridobis(4-phenylpyridine-κN)palladium(II)
The asymmetric unit of the title complex, [PdCl(2)(C(11)H(9)N)(2)], contains one half of a neutral Pd(II) complex, with the complete mol-ecule generated by the application of a twofold rotation axis; the N-Pd-N atoms lie on the axis. The Pd(II) ion has a trans-Cl(2)N(2) square-planar coordination geometry defined by two N atoms from two 4-phenyl-pyridine ligands and two Cl(-) anions. In the ref...
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In the title compound, [PdCl(2)(C(7)H(9)NO)(2)], the Pd atom is situated on a crystallographic centre of inversion. The coordination environment of the Pd atom shows a slightly distorted square-planar geometry. The crystal structure exhibits weak inter-molecular Pd⋯Cl inter-actions, with Pd⋯Cl distances of 3.6912 (6) Å. A chain-like arrangement of mol-ecules realized by inter-molecular N-H⋯Cl h...
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